TY - JOUR
T1 - POFA-engineered alkali-activated cementitious composite performance in acid environment
AU - Salami, Babatunde Abiodun
AU - Johari, Megat Azmi Megat
AU - Ahmad, Zainal Arifin
AU - Maslehuddin, Mohammed
N1 - Publisher Copyright:
© 2017 Japan Concrete Institute.
PY - 2017/11
Y1 - 2017/11
N2 - The durability performance of palm oil fuel ash engineered alkali-activated cementitious composite (POFA-EACC) mortar exposed to different acid solutions is assessed in this study. 50 mm cubic specimens used for the study were prepared from 100% POFA, alkali-activator (Na2SiO3(aq)/NaOH(aq)) ratios of 2.5, different molarities (10, 12 and 14 M) of NaOH(aq) and 2% volume fraction of polyvinyl alcohol (PVA) fibres. Specimens were exposed to 10% H2SO4(aq), 10% HNO3(aq) and 10% HCl(aq) at pH of 0.56, 0.52 and 0.42 respectively for 3, 6 and 9 months, with unexposed specimens as control. Small changes in compressive strength were identified with POFA mortar specimens during exposure to H2SO4(aq), while exposure to HNO3(aq) and HCl(aq) greatly reduced the strength of the POFA mortar specimens. The results were supported through microstructural examinations using SEM, while the characterization was done using XRD and FTIR. The high resistance of POFA-EACC mortar to H2SO4(aq) is the contribution received through the formation of gypsum, which hinders the infiltration of more acids into the matrix microstructure.
AB - The durability performance of palm oil fuel ash engineered alkali-activated cementitious composite (POFA-EACC) mortar exposed to different acid solutions is assessed in this study. 50 mm cubic specimens used for the study were prepared from 100% POFA, alkali-activator (Na2SiO3(aq)/NaOH(aq)) ratios of 2.5, different molarities (10, 12 and 14 M) of NaOH(aq) and 2% volume fraction of polyvinyl alcohol (PVA) fibres. Specimens were exposed to 10% H2SO4(aq), 10% HNO3(aq) and 10% HCl(aq) at pH of 0.56, 0.52 and 0.42 respectively for 3, 6 and 9 months, with unexposed specimens as control. Small changes in compressive strength were identified with POFA mortar specimens during exposure to H2SO4(aq), while exposure to HNO3(aq) and HCl(aq) greatly reduced the strength of the POFA mortar specimens. The results were supported through microstructural examinations using SEM, while the characterization was done using XRD and FTIR. The high resistance of POFA-EACC mortar to H2SO4(aq) is the contribution received through the formation of gypsum, which hinders the infiltration of more acids into the matrix microstructure.
UR - http://www.scopus.com/inward/record.url?scp=85037067831&partnerID=8YFLogxK
U2 - 10.3151/jact.15.684
DO - 10.3151/jact.15.684
M3 - Article
AN - SCOPUS:85037067831
SN - 1346-8014
VL - 15
SP - 684
EP - 699
JO - Journal of Advanced Concrete Technology
JF - Journal of Advanced Concrete Technology
IS - 11
ER -